Hello & welcome Alan,
I can't seem to find the ISO overriding option though, where is it and what's the name?
You'll find it in the CHDK menu "
Extra Photo Operations" --> "
Override ISO value"
Hint: quote from the wikia,
Allbest Firmware Usage:
"When changing values in any CHDK menu options or script-variable selections you may use the zoom-rocker toggle to quickly switch between changing the 1s, 10s, 100s, 1000s, and 10,000s unit. A red-highlighted indicator will appear in the upper left of your EVF/LCD to let you know which unit you are changing."
Oh, and speaking of long exposures, I tried 65 sec just for the goof and I noticed something strange.. the top-left of the image appears blue even though there's no blue light source/object there. Is the S5 sensor that bad?
I have no S5, but this seems to be sensor noise, caused by heat parts near the sensor...
On exposures > 1 seconds normally a dark frame subtraction is done (by the Canon firmware), you can control this in the CHDK menu "RAW Parameters" --> "Noise reduction", it's for RAW and JPG files, see
Wikia: RAW parameters menu.
Perhaps one of the S5 users can be more helpfull...