You should be able to do this with a photodiode and script control of one of the LEDs on the powershot.
What kind of motion detection do you need? Are you doing light detection or human motion or what?One cheap solution would be getting a PIR and plugging it into the 2.5mm jack (I thought 5D used N3? ...). Cost would be $10-15 and would detect humans and animals. Put in a timer circuit with a pot and you could have it hit your shutter button on an adjustable delay.
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