So, according to this, in a studio, at the point in time that the chdkptp 'shoot' command is issued, lighting conditions = ambient. Focus / exposure / [aperture? do P&S have aperture control]
Some have adjustable aperture, some don't. Most of the ixus and recent A series do not.
are automatically set based on these 'ambient' conditions [is that assumption correct ?].
This depends on the canon shooting mode, and whether you have override and settings using CHDK.
However, if fast action capture is required based on subsequent tens of microsecond studio-flash capture then ambient light auto generated exposure / focus / aperture settings may be [will be ?] sub-optimal.
No consumer camera can adjust the exposure while the flash is in progress.

When the camera uses it's own flash, it knows something about the brightness, distance of the subject and makes a guess. This is often not very good...
If these settings can be, programatically, set & 'locked in', based on the expectation of future studio flash conditions [via chdkptp commands/script prior to chdkptp 'shoot'] so that the 'ambient light' "Multi-Camera Synchronization...Enable Sync...This allows CHDK on several cameras to focus, adjust exposure, setup the flash and then wait for a shared signal to complete the shot" settings [somehow
] have no impact on the 'locked-in expected flash-condition' settings then [I think] that's what i'd like [but my assumption is that this is not possible].
I'm still not totally clear what you expect to happen, but
1) using CHDK you can set shutter, ISO, focus (on most cameras) and aperture (if present) to any valid value.
2) You should be able to determine the setting needed to get correct exposure with your flash setup.
It sounds like you may be misunderstanding the remote page. The remote code doesn't have anything to do with setting correct exposure or focus. The part you quoted just means that the remote code allows the camera to wait
after those things have been set. It does not set them, you have to arrange that yourself using manual mode, camera auto exposure, or some script or override.